Many anomalies before the 2009 L'Aquila earthquake were reported but not synergically analyzed referring to geosystem coupling. We investigated changes of multiple hydrothermal parameters in coversphere and atmosphere and studied 3-D evolution of b value in lithosphere. Quasi-synchronism of pre-earthquake anomalies georelating to particular thrusts and local topography are revealed. A geosphere coupling mode is proposed interpreting the function of CO₂-rich crust fluids on local LCA coupling.