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<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0" article-type="research-article">
  <front>
    <journal-meta><journal-id journal-id-type="publisher">NHESS</journal-id><journal-title-group>
    <journal-title>Natural Hazards and Earth System Sciences</journal-title>
    <abbrev-journal-title abbrev-type="publisher">NHESS</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Nat. Hazards Earth Syst. Sci.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1684-9981</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/nhess-22-213-2022</article-id><title-group><article-title>Precipitation stable isotopic signatures of tropical cyclones in
Metropolitan Manila, Philippines, show significant negative <?xmltex \hack{\break}?>isotopic
excursions</article-title><alt-title>Precipitation stable isotopic signatures of tropical cyclones in
Metropolitan Manila</alt-title>
      </title-group><?xmltex \runningtitle{Precipitation stable isotopic signatures of tropical cyclones in
Metropolitan Manila}?><?xmltex \runningauthor{D.~Jackisch et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Jackisch</surname><given-names>Dominik</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Yeo</surname><given-names>Bi Xuan</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="yes" rid="aff1 aff2">
          <name><surname>Switzer</surname><given-names>Adam D.</given-names></name>
          <email>aswitzer@ntu.edu.sg</email>
        <ext-link>https://orcid.org/0000-0002-4352-7852</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>He</surname><given-names>Shaoneng</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-4948-2859</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Cantarero</surname><given-names>Danica Linda M.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Siringan</surname><given-names>Fernando P.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff2 aff4">
          <name><surname>Goodkin</surname><given-names>Nathalie F.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-9697-5520</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Earth Observatory of Singapore, Nanyang Technological University,
Singapore 639798</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Asian School of the Environment, Nanyang Technological University,
Singapore 639798</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Marine Science Institute, University of the Philippines Diliman,
Quezon City 1101, Philippines</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>American Museum of Natural History, New York, New York 10024, USA</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Adam D. Switzer (aswitzer@ntu.edu.sg)</corresp></author-notes><pub-date><day>28</day><month>January</month><year>2022</year></pub-date>
      
      <volume>22</volume>
      <issue>1</issue>
      <fpage>213</fpage><lpage>226</lpage>
      <history>
        <date date-type="received"><day>24</day><month>October</month><year>2019</year></date>
           <date date-type="rev-request"><day>2</day><month>January</month><year>2020</year></date>
           <date date-type="rev-recd"><day>1</day><month>December</month><year>2021</year></date>
           <date date-type="accepted"><day>4</day><month>December</month><year>2021</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2022 </copyright-statement>
        <copyright-year>2022</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://nhess.copernicus.org/articles/.html">This article is available from https://nhess.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://nhess.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://nhess.copernicus.org/articles/.pdf</self-uri>
      <abstract><title>Abstract</title>

      <p id="d1e158">Tropical cyclones have devastating impacts on the environment, economies,
and societies and may intensify in the coming decades due to climate
change. Stable water isotopes serve as tracers of the hydrological cycle, as
isotope fractionation processes leave distinct precipitation isotopic
signatures. Here we present a record of daily precipitation isotope
measurements from March 2014 to October 2015 for Metropolitan Manila, a
first-of-a-kind dataset for the Philippines and Southeast Asia. We show that
precipitation isotopic variation at our study site is closely related to
tropical cyclones. The most negative shift in <inline-formula><mml:math id="M1" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values
(<inline-formula><mml:math id="M2" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13.84</mml:mn></mml:mrow></mml:math></inline-formula> ‰) leading to a clear isotopic signal was
caused by Typhoon Rammasun, which directly hit Metropolitan Manila. The
average <inline-formula><mml:math id="M3" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O value of precipitation associated with tropical
cyclones is <inline-formula><mml:math id="M4" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10.24</mml:mn></mml:mrow></mml:math></inline-formula> ‰, whereas the mean isotopic value
for rainfall associated with non-cyclone events is <inline-formula><mml:math id="M5" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5.29</mml:mn></mml:mrow></mml:math></inline-formula> ‰. Further, the closer the storm track is to the sampling
site, the more negative the isotopic values are, indicating that in situ isotope
measurements can provide a direct linkage between isotopes and typhoon
activities in the Philippines.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e222">The Philippines, an archipelago with a fast-growing population clustered along
the coastline, is one of the most vulnerable countries to climate change
(Cinco et al., 2014). It is especially prone to the devastating effects of
tropical cyclones. Thus, it is considered a hotspot region for
hydrometeorological disasters
(Cinco
et al., 2014; Cruz et al., 2013; Takagi and Esteban, 2016). There is a clear
need for developing a better understanding of tropical cyclone (TC) dynamics
and cyclone histories in the context of prediction that may allow government
agencies to implement proper mitigation and adaptation policies. Nine TCs
per year made landfall on average between 1951 and 2013 in the Philippines.
The number of TCs not making landfall but reaching Philippine waters is
substantially higher with 19.4 per year
(Cinco et al., 2016). The changing climate
and associated warming of the surface ocean will likely increase the
intensity of tropical cyclones in the future
(Emanuel,
2005; Webster et al., 2005; Woodruff et al., 2013).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e228">Costliest typhoons in the Philippines. Two devastating typhoons,
Rammasun and Koppu (ranking 3 and 7), occurred during our study period and
made landfall. Damage in US dollars (USD) based on each time of TC occurrence (not
adjusted to current inflation rates).</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="7">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:colspec colnum="5" colname="col5" align="left"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="left"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Rank</oasis:entry>
         <oasis:entry colname="col2">Name (local name)</oasis:entry>
         <oasis:entry colname="col3">Category (Saffir–</oasis:entry>
         <oasis:entry colname="col4">Period of occurrence</oasis:entry>
         <oasis:entry colname="col5">Damage in USD</oasis:entry>
         <oasis:entry colname="col6">Fatalities</oasis:entry>
         <oasis:entry colname="col7">Part of our</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3">Simpson scale)</oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7">dataset</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">1.</oasis:entry>
         <oasis:entry colname="col2">Haiyan (Yolanda)</oasis:entry>
         <oasis:entry colname="col3">Category 5</oasis:entry>
         <oasis:entry colname="col4">2–11 November 2013</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M6" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> USD 2.06 billion</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M7" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">6000</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7">No</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2.</oasis:entry>
         <oasis:entry colname="col2">Bopha (Pablo)</oasis:entry>
         <oasis:entry colname="col3">Category 5</oasis:entry>
         <oasis:entry colname="col4">2–10 December 2012</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M8" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> USD 977 million</oasis:entry>
         <oasis:entry colname="col6">1067</oasis:entry>
         <oasis:entry colname="col7">No</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">3.</oasis:entry>
         <oasis:entry colname="col2">Rammasun (Glenda)</oasis:entry>
         <oasis:entry colname="col3">Category 5</oasis:entry>
         <oasis:entry colname="col4">12–17 July 2014</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M9" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> USD 880 million</oasis:entry>
         <oasis:entry colname="col6">106</oasis:entry>
         <oasis:entry colname="col7">Yes</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">7.</oasis:entry>
         <oasis:entry colname="col2">Koppu (Lando)</oasis:entry>
         <oasis:entry colname="col3">Category 4</oasis:entry>
         <oasis:entry colname="col4">12–21 October 2015</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M10" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> USD 310 million</oasis:entry>
         <oasis:entry colname="col6">62</oasis:entry>
         <oasis:entry colname="col7">Yes</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d1e231">References: Alojado and Padua (2015), Lagmay et al. (2015), NDRRMC (2012, 2014, 2015), and Soria et al. (2016).</p></table-wrap-foot></table-wrap>

      <p id="d1e437">The Philippines was struck by several devastating TCs in recent years (Table 1). Typhoon Haiyan (2013), which tracked over the Visayas, has been the
costliest TC to date (<inline-formula><mml:math id="M11" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> USD 2.06 billion in 2013), with strong
winds and intense storm surges inundating coastal areas resulting in more
than 6000 fatalities
(Alojado
and Padua, 2015; Lagmay et al., 2015; Soria et al., 2016). Typhoon Rammasun,
which made landfall in July 2014, is ranked number 3 with <inline-formula><mml:math id="M12" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> USD 880 million in damage in 2014 (Alojado and Padua, 2015;
NDRRMC, 2014); 80 % of the strongest typhoons making landfall in
the Philippines over the last 3 decades developed during periods of higher-than-average sea surface<?pagebreak page214?> temperature (SST), which supports the hypothesis that
TC intensities are projected to rise in the future with an increase in
global temperatures (Guan
et al., 2018; Webster et al., 2005; Takagi and Esteban, 2016). For
example, SST was found to be anomalously high and reaching 29.6 <inline-formula><mml:math id="M13" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C during the formation of Typhoon Haiyan (Takagi and
Esteban, 2016). The average Philippine ocean SST for the period from 1945
to 2014 (basin between 6–18<inline-formula><mml:math id="M14" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 120–140<inline-formula><mml:math id="M15" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E) is <inline-formula><mml:math id="M16" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">28.5</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M17" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C based on the National Oceanic and Atmospheric Administration Extended Reconstructed Sea Surface
Temperature dataset, version 5 (NOAA ERSST v5)
(Takagi and Esteban, 2016). By the end of the
21st century, average typhoon intensity in the low-latitude
northwestern Pacific is predicted to increase by 14 % due to rising ocean
temperatures (Mei et al., 2015).</p>
      <p id="d1e502">A few studies have demonstrated the potential to investigate tropical
cyclones using stable water isotopes
(Good
et al., 2014; Lawrence et al., 2002; Munksgaard et al., 2015; Pape et al.,
2010). As dynamic tracers of hydrological processes, stable water isotopes
(<inline-formula><mml:math id="M18" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H and <inline-formula><mml:math id="M19" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O) can provide insights into the water
and energy budgets of TCs (Good et
al., 2014; Lawrence and Gedzelman, 1996). In the regions with general TC
occurrence, significantly lower <inline-formula><mml:math id="M20" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H and <inline-formula><mml:math id="M21" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values are associated with TC rainfall due to strong isotope fractionation
processes, compared to other tropical rain events
(Lawrence, 1998; Lawrence and Gedzelman, 1996).
Furthermore, <inline-formula><mml:math id="M22" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H and <inline-formula><mml:math id="M23" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O have been used
successfully to interpret TC history from paleoarchives, such as tree rings
and speleothems (Oliva et al., 2017). For instance,
tree-ring cellulose isotope proxies have recorded the most recent 220 years of
cyclones in the southeastern USA (Miller et al.,
2006); similarly, high-resolution isotopic analysis of tree rings from the
eastern US revealed the occurrence of hurricanes in 2004
(Li et al., 2011). A 23-year stalagmite record from Central America was used to reconstruct past
TC activity (Frappier et al., 2007),
and isotope signals from an 800-year stalagmite record were used to
reconstruct past TC frequencies in northeastern Australia
(Nott et al., 2007). Interpretation of TC
history in paleotempestology from paleoarchives is based on the fact that
TCs leave distinct isotopic signatures on precipitation, possibly providing
information on TC evolution and structure
(Lawrence et al., 2002).</p>
      <p id="d1e572">The depletion in stable isotopes has been attributed to the high
condensation levels and strong isotopic exchanges between inflowing water
vapour and falling raindrops in cyclonic rainfall bands, resulting in a
temporal decrease of isotopic values throughout a rain event (i.e. amount
effect) (Lawrence, 1998; Lawrence and
Gedzelman, 1996). Isotopic depletion can be further enhanced by a TC's thick,
deep clouds; relatively large storm size; and longevity
(Lawrence, 1998). Furthermore, while isotopic
depletion increases inwards towards the eye wall of the storm
(Lawrence and Gedzelman, 1996), isotope ratios inside the inner
eye wall region are relatively enriched, likely due to an intensive isotopic
moisture recharge with heavy isotopes from sea spray
(Fudeyasu et al.,
2008; Gedzelman et al., 2003). These findings are based on work conducted in
the 1990s in Puerto Rico and on the southern and eastern coasts of the
United States. More recently, these previous findings have been confirmed by
studying TCs which occurred in a few other regions, such as in China or
Australia
(Chakraborty
et al., 2016; Fudeyasu et al., 2008; Good et al., 2014; Munksgaard et al.,
2015; Xu et al., 2019).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><?xmltex \def\figurename{Figure}?><label>Figure 1</label><caption><p id="d1e577">Metropolitan Manila sampling site and TC tracks of 2014 and 2015
seasons. Three different sized circles indicate the distance to the sampling
site with the outermost one being 500 km in radius. Cyclone tracks are
colour-coded according to the typhoon classification from the Regional
Specialized Meteorological Centre (RSMC) Tokyo. Cyclones in grey
refer to a TC outside the 500 km radius.</p></caption>
        <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://nhess.copernicus.org/articles/22/213/2022/nhess-22-213-2022-f01.png"/>

      </fig>

      <p id="d1e586">The above-mentioned studies are geographically limited to a few locations
globally, with no studies in Southeast Asia and the Philippines in
particular. Here, we present the first such study for the Philippines, with
daily isotope measurements of precipitation from Metropolitan Manila (the
National Capital Region) spanning from March 2014 to October 2015. During
the study period, nine tropical cyclones passed by or made landfall within
500 km of the sampling site (Fig. 1). The main objectives of this research
are the following:
<list list-type="bullet"><list-item>
      <p id="d1e591">to understand if there is an isotopic variation in precipitation associated
with TC landfall in the Philippines and if tropical cyclones leave clear
isotopic signals</p></list-item><list-item>
      <p id="d1e595">to identify the isotopic signals measured for Metropolitan Manila and the
intensity of the isotopic depletion associated with TC activities and to
identify how they are represented spatially</p></list-item><list-item>
      <p id="d1e599">to understand the isotopic variation with distance from the TC track in the
Philippines.</p></list-item></list>
Our findings provide a baseline dataset for reconstruction of typhoon
activities using stable isotopes and contribute to a better understanding of
past and future TC activities in the Philippines.</p>
</sec>
<?pagebreak page215?><sec id="Ch1.S2">
  <label>2</label><title>Materials and methods</title>
<sec id="Ch1.S2.SS1">
  <label>2.1</label><title>Site description</title>
      <p id="d1e618">The Philippines is a Southeast Asian country comprising more than 7000
islands located in the northwestern Pacific between 4<inline-formula><mml:math id="M24" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>40<inline-formula><mml:math id="M25" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> and
21<inline-formula><mml:math id="M26" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>10<inline-formula><mml:math id="M27" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> N and 116<inline-formula><mml:math id="M28" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>40<inline-formula><mml:math id="M29" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> and 126<inline-formula><mml:math id="M30" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>34<inline-formula><mml:math id="M31" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> E (Fig. 1). The country experiences an average annual rainfall of about 2000 mm,
influenced by two monsoon seasons, the northeast monsoon from November to
April and the southwest monsoon from May to October
(Cinco et al., 2014). About 35 %
of the annual rainfall is related to TC activity, while its contribution
rises to about 50 % for Luzon and decreases to 4 % for the southern
island of Mindanao (Cinco et al.,
2016). Part of the rainfall amount in the Philippines is of orographic
nature due to north–south-oriented mountain ranges of more than 1000 m
spanning the largest islands of Luzon and Mindanao
(Villafuerte et
al., 2014). The majority of the steadily growing population in the
Philippines (101 million as of the 2017 census) lives in densely populated,
low-elevation areas close to the coastlines
(Cinco
et al., 2014, 2016; Philippine Statistics Authority, 2017).</p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>Isotopic data</title>
      <?pagebreak page216?><p id="d1e702">In total, 186 daily precipitation samples were collected from 11 March 2014
to 27 October 2015 using a Palmex collector
(Gröning et al., 2012) at the
Marine Science Institute of the University of the Philippines Diliman
located in Quezon City, which is a part of Metropolitan Manila. The rain
station was installed on the rooftop of the Marine Science Institute
(14<inline-formula><mml:math id="M32" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>39<inline-formula><mml:math id="M33" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>02.5<inline-formula><mml:math id="M34" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>′</mml:mo><mml:mo>′</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> N, 121<inline-formula><mml:math id="M35" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>04<inline-formula><mml:math id="M36" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>08.6<inline-formula><mml:math id="M37" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>′</mml:mo><mml:mo>′</mml:mo></mml:mrow></mml:msup></mml:math></inline-formula> E), which is centrally
situated in the campus and surrounded by trees and various green spaces. The
rooftop location proved ideal for rainwater collection, as it allowed for
unobstructed access to rainwater without any potential sources of
contamination. Samples were collected daily at 10:00 and transferred without
headspace to 30 mL HDPE (high-density polyethylene) bottles for storage prior to analysis. Samples were
sent to the Earth Observatory of Singapore, Nanyang Technological
University, Singapore, and were analysed for stable isotopes using a Picarro
L1230-<inline-formula><mml:math id="M38" display="inline"><mml:mi>i</mml:mi></mml:math></inline-formula> laser spectroscopy instrument. We followed the procedures described
by Van Geldern and Barth (2012)
for post-run corrections and calibration. Three in-house water standards
used for calibration include KONA (0.02 ‰ of <inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O; 0.25 ‰ of <inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H), TIBET (<inline-formula><mml:math id="M41" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">19.11</mml:mn></mml:mrow></mml:math></inline-formula> ‰ of <inline-formula><mml:math id="M42" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O; <inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">143.60</mml:mn></mml:mrow></mml:math></inline-formula> ‰ of
<inline-formula><mml:math id="M44" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H), and ELGA (<inline-formula><mml:math id="M45" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4.25</mml:mn></mml:mrow></mml:math></inline-formula> ‰ of <inline-formula><mml:math id="M46" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O; <inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">27.16</mml:mn></mml:mrow></mml:math></inline-formula> ‰ of <inline-formula><mml:math id="M48" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H). They are
calibrated against the international reference water standards VSMOW2 (Vienna Standard Mean Ocean Water 2) and SLAP2 (Standard Light Antarctic Precipitation 2).
Long-term analysis of our QA/QC (quality assurance/quality control) standards yields a precision of 0.04 ‰ for <inline-formula><mml:math id="M49" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and 0.2 ‰ for <inline-formula><mml:math id="M50" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H. We used <inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and <inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H to
calculate deuterium excess, which is defined as d-excess <inline-formula><mml:math id="M53" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H <inline-formula><mml:math id="M54" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M55" display="inline"><mml:mrow><mml:mn mathvariant="normal">8</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and is commonly regarded to reflect
evaporation conditions of moisture source regions.</p>
</sec>
<sec id="Ch1.S2.SS3">
  <label>2.3</label><title>Cyclone track data</title>
      <p id="d1e969">The International Best Track Archive for Climate Stewardship (IBTrACS)
dataset contains global TC best-track data and is a joint effort of various
regional meteorological institutions and centres that are part of the World
Meteorological Organization (WMO). The data are publicly available and
comprise information on a storm's eye/centre with its coordinates, wind speed,
and pressure, etc., with a temporal resolution of 6 h
(Knapp
et al., 2010a, b; Rios Gaona et al., 2018). Apart from visualization of cyclone
paths, we used the dataset to calculate the spatial distance between the coordinates of a
storm's eye and our sampling site.</p>
</sec>
<sec id="Ch1.S2.SS4">
  <label>2.4</label><title>Satellite precipitation data</title>
      <p id="d1e980">We used version 5 of the IMERG Final daily product (Integrated Multi-satellitE Retrievals for GPM, Global Precipitation Measurement), a remotely sensed
precipitation dataset from satellites, to highlight cyclonic tracks and
precipitation patterns of several TCs passing by Metropolitan Manila and
to identify which rainfall events were not affected by cyclonic activity
but instead were associated with local or other regional convection
activities. Such a dataset is beneficial, as it provides quasi-global
grid-based rainfall estimates for land and the oceans
(Poméon et
al., 2017). The Integrated Multi Satellite Retrievals for GPM (IMERG) dataset from
the Global Precipitation Measurement (GPM) programme with a fine 0.1<inline-formula><mml:math id="M56" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>
grid size (Huffman et al., 2017, 2019) has been
available since March 2014 and provides precipitation data in different
temporal resolutions, such as half-hourly or daily. Such satellite rainfall
data have been previously utilized to show TC tracks and related rainfall
intensities
(Rios
Gaona et al., 2018; Villarini et al., 2011).</p>
</sec>
<sec id="Ch1.S2.SS5">
  <label>2.5</label><title>Rainfall, temperature, and relative humidity data</title>
      <p id="d1e1001">Daily rainfall, mean daily relative humidity, and mean daily temperature data
were obtained from the Philippine Atmospheric, Geophysical and Astronomical
Services Administration (PAGASA), which maintains a rainfall monitoring
station about 2.7 km away from our sampling site. The data are freely
available for the period 2013 to 2017 and can be accessed on the Philippines
Freedom of Information website (<uri>https://www.foi.gov.ph/</uri>, last access: 18 October 2019).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><?xmltex \currentcnt{2}?><?xmltex \def\figurename{Figure}?><label>Figure 2</label><caption><p id="d1e1009">Time series of daily variations of <inline-formula><mml:math id="M57" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, <inline-formula><mml:math id="M58" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H, d-excess, temperature, relative humidity, and precipitation amount
at Metropolitan Manila, Philippines. Please note that the date format in this figure is month/year.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://nhess.copernicus.org/articles/22/213/2022/nhess-22-213-2022-f02.png"/>

        </fig>

</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Results</title>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Isotopic variation of stable isotopes in daily precipitation</title>
      <?pagebreak page217?><p id="d1e1056">A total of 186 daily precipitation samples were collected during
the 19 months of the study period spanning from 11 March 2014 to 27 October 2015 in Metropolitan Manila. Their stable isotope compositions show large
seasonal isotopic variability; <inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O ranges from 4 ‰ to <inline-formula><mml:math id="M60" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13.84</mml:mn></mml:mrow></mml:math></inline-formula> ‰, and <inline-formula><mml:math id="M61" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H ranges
from 16.84 ‰ to <inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">99.1</mml:mn></mml:mrow></mml:math></inline-formula> ‰ (Fig. 2).
The highest <inline-formula><mml:math id="M63" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O value of 4 ‰ was observed on 9 April 2014 during the annual dry period, whereas the lowest <inline-formula><mml:math id="M64" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O value of <inline-formula><mml:math id="M65" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13.84</mml:mn></mml:mrow></mml:math></inline-formula> ‰ was observed on 16 September 2014
in association with TC activity. The mean <inline-formula><mml:math id="M66" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O value of precipitation
at the study site is <inline-formula><mml:math id="M67" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5.29</mml:mn></mml:mrow></mml:math></inline-formula> ‰ for non-TC rain systems,
while TCs, as large regional convective systems, have the potential to cause
a change in <inline-formula><mml:math id="M68" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> values of up to almost 9 ‰ relative to the mean. The average <inline-formula><mml:math id="M69" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O value of the nine TCs that
tracked within <inline-formula><mml:math id="M70" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> km from the sampling site is <inline-formula><mml:math id="M71" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10.24</mml:mn></mml:mrow></mml:math></inline-formula> ‰ (SD of 2.11), a factor of 2 larger than the mean
from non-TC precipitation (average is <inline-formula><mml:math id="M72" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5.29</mml:mn></mml:mrow></mml:math></inline-formula> ‰, SD of
2.64).</p>
      <p id="d1e1204">An inter-annual variation of stable isotopes in precipitation is observed in
the time series of Metropolitan Manila, where the generally humid summer
months are characterized by heavy rainfall and exhibit lower isotope values
compared to the rest of the year (Fig. 2). The precipitation isotopes are
characterized by slightly higher values during winter and spring, when
temperatures and relative humidity are lower with less frequent rainfall.
Especially early 2015 shows drier conditions with sporadic rainfall and
relative humidity levels of about 60 % to 70 %. This is also reflected
in the precipitation collected on 1 March 2015 with <inline-formula><mml:math id="M73" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O of
0.01 ‰ and <inline-formula><mml:math id="M74" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H of 9.8 ‰, respectively. Although d-excess shows relatively high temporal
variability, ranging from <inline-formula><mml:math id="M75" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">15.18</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to 24.31 ‰, it largely clusters in a small range between 5 ‰ and 15 ‰.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3"><?xmltex \currentcnt{3}?><?xmltex \def\figurename{Figure}?><label>Figure 3</label><caption><p id="d1e1241">Local meteoric water line (LMWL) established for Metropolitan
Manila, Philippines. The red dotted line represents the global meteoric
water line (GMWL) (<inline-formula><mml:math id="M76" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H <inline-formula><mml:math id="M77" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M78" display="inline"><mml:mrow><mml:mn mathvariant="normal">8</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O <inline-formula><mml:math id="M79" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> 10; Craig,
1961).</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://nhess.copernicus.org/articles/22/213/2022/nhess-22-213-2022-f03.png"/>

        </fig>

      <p id="d1e1291">Based on the daily isotope measurements of rainfall events between 2014 and
2015, we determined the LMWL (local meteoric water line) for the study site
to be <inline-formula><mml:math id="M80" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H <inline-formula><mml:math id="M81" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M82" display="inline"><mml:mrow><mml:mn mathvariant="normal">7.2674</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O <inline-formula><mml:math id="M83" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> 5.4103 (Fig. 3),
indicating that slope and intercept of the LMWL are lower due to the
influence of tropical precipitation compared to the GMWL (global meteoric
water line) with <inline-formula><mml:math id="M84" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H <inline-formula><mml:math id="M85" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M86" display="inline"><mml:mrow><mml:mn mathvariant="normal">8</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O <inline-formula><mml:math id="M87" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> 10
(Craig, 1961).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><?xmltex \currentcnt{4}?><?xmltex \def\figurename{Figure}?><label>Figure 4</label><caption><p id="d1e1377">Correlations between daily <inline-formula><mml:math id="M88" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values and daily
values of d-excess, precipitation amount, temperature, and relative humidity.
Linear regression line, correlation coefficient (<inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>), slope,
and intercept are shown in each plot. Samples associated with a TC are shown in
red similar to Fig. 5.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://nhess.copernicus.org/articles/22/213/2022/nhess-22-213-2022-f04.png"/>

        </fig>

      <p id="d1e1408">In order to assess meteorological controls on the isotopic composition of
daily precipitation at Metropolitan Manila, we investigated the correlation
between <inline-formula><mml:math id="M90" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, daily precipitation amount, daily mean
temperature, and daily mean relative humidity. Additionally, <inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O is compared to d-excess (<inline-formula><mml:math id="M92" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">187</mml:mn></mml:mrow></mml:math></inline-formula>) (Fig. 4). We found that <inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O is weakly correlated to d-excess
(<inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.2187</mml:mn></mml:mrow></mml:math></inline-formula>), precipitation amount (<inline-formula><mml:math id="M95" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.1087</mml:mn></mml:mrow></mml:math></inline-formula>), and relative
humidity (<inline-formula><mml:math id="M96" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.1323</mml:mn></mml:mrow></mml:math></inline-formula>). No association is observed between <inline-formula><mml:math id="M97" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and temperature (<inline-formula><mml:math id="M98" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.0338</mml:mn></mml:mrow></mml:math></inline-formula>).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2" specific-use="star"><?xmltex \currentcnt{2}?><label>Table 2</label><caption><p id="d1e1531">Monthly average values of the 19-month time series of <inline-formula><mml:math id="M99" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, <inline-formula><mml:math id="M100" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H, d-excess, and meteorological parameters
(temperature and relative humidity). Precipitation values are reported
as monthly totals.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="7">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Month</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M101" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O (‰)</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M102" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H (‰)</oasis:entry>
         <oasis:entry colname="col4">d-excess (‰)</oasis:entry>
         <oasis:entry colname="col5">Precipitation (mm)</oasis:entry>
         <oasis:entry colname="col6">Temperature (<inline-formula><mml:math id="M103" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>
         <oasis:entry colname="col7">Relative humidity (%)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Mar 2014</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M104" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.43</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M105" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.62</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">2.82</oasis:entry>
         <oasis:entry colname="col5">19.2</oasis:entry>
         <oasis:entry colname="col6">27.1</oasis:entry>
         <oasis:entry colname="col7">70.0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Apr 2014</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M106" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.53</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M107" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4.54</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M108" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.33</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5">22.6</oasis:entry>
         <oasis:entry colname="col6">28.8</oasis:entry>
         <oasis:entry colname="col7">68.9</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">May 2014</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M109" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.89</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M110" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13.50</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">9.63</oasis:entry>
         <oasis:entry colname="col5">99.1</oasis:entry>
         <oasis:entry colname="col6">29.8</oasis:entry>
         <oasis:entry colname="col7">71.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Jun 2014</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M111" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6.90</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M112" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">44.90</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">10.28</oasis:entry>
         <oasis:entry colname="col5">239.1</oasis:entry>
         <oasis:entry colname="col6">28.7</oasis:entry>
         <oasis:entry colname="col7">81.2</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Jul 2014</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M113" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6.46</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M114" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">41.68</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">10.04</oasis:entry>
         <oasis:entry colname="col5">455.4</oasis:entry>
         <oasis:entry colname="col6">27.5</oasis:entry>
         <oasis:entry colname="col7">86.6</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Aug 2014</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M115" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6.39</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M116" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">42.63</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">8.51</oasis:entry>
         <oasis:entry colname="col5">420.7</oasis:entry>
         <oasis:entry colname="col6">27.4</oasis:entry>
         <oasis:entry colname="col7">85.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Sep 2014</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M117" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">7.29</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">48.57</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">9.76</oasis:entry>
         <oasis:entry colname="col5">654.9</oasis:entry>
         <oasis:entry colname="col6">27.4</oasis:entry>
         <oasis:entry colname="col7">85.3</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Oct 2014</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5.24</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">31.73</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">10.19</oasis:entry>
         <oasis:entry colname="col5">406.4</oasis:entry>
         <oasis:entry colname="col6">26.9</oasis:entry>
         <oasis:entry colname="col7">84.2</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Nov 2014</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4.39</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">27.64</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">7.48</oasis:entry>
         <oasis:entry colname="col5">90.5</oasis:entry>
         <oasis:entry colname="col6">26.9</oasis:entry>
         <oasis:entry colname="col7">80.0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Dec 2014</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M123" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4.72</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M124" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">28.00</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">9.79</oasis:entry>
         <oasis:entry colname="col5">154.6</oasis:entry>
         <oasis:entry colname="col6">26.0</oasis:entry>
         <oasis:entry colname="col7">81.4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Jan 2015</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M125" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6.67</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M126" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">44.41</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">8.97</oasis:entry>
         <oasis:entry colname="col5">29.2</oasis:entry>
         <oasis:entry colname="col6">24.6</oasis:entry>
         <oasis:entry colname="col7">77.8</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Feb 2015</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.66</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M128" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">19.70</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M129" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">14.41</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5">2.7</oasis:entry>
         <oasis:entry colname="col6">25.5</oasis:entry>
         <oasis:entry colname="col7">70.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Mar 2015</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M130" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.70</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">3.95</oasis:entry>
         <oasis:entry colname="col4">9.54</oasis:entry>
         <oasis:entry colname="col5">6.6</oasis:entry>
         <oasis:entry colname="col6">26.8</oasis:entry>
         <oasis:entry colname="col7">62.9</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Apr 2015</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5">64.8</oasis:entry>
         <oasis:entry colname="col6">29.1</oasis:entry>
         <oasis:entry colname="col7">62.0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">May 2015</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5">74.6</oasis:entry>
         <oasis:entry colname="col6">29.7</oasis:entry>
         <oasis:entry colname="col7">68.4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Jun 2015</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M131" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5.52</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M132" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">34.47</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">9.71</oasis:entry>
         <oasis:entry colname="col5">328.7</oasis:entry>
         <oasis:entry colname="col6">29.3</oasis:entry>
         <oasis:entry colname="col7">73.1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Jul 2015</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M133" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6.04</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M134" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">36.69</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">11.61</oasis:entry>
         <oasis:entry colname="col5">28.6</oasis:entry>
         <oasis:entry colname="col6">27.8</oasis:entry>
         <oasis:entry colname="col7">80.5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Aug 2015</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M135" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5.25</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M136" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">32.28</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">9.74</oasis:entry>
         <oasis:entry colname="col5">459.3</oasis:entry>
         <oasis:entry colname="col6">28.0</oasis:entry>
         <oasis:entry colname="col7">81.1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Sep 2015</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M137" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6.12</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M138" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">37.07</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">11.86</oasis:entry>
         <oasis:entry colname="col5">444.8</oasis:entry>
         <oasis:entry colname="col6">28.0</oasis:entry>
         <oasis:entry colname="col7">81.0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Oct 2015</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M139" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6.27</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M140" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">40.80</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">6.60</oasis:entry>
         <oasis:entry colname="col5">250.5</oasis:entry>
         <oasis:entry colname="col6">27.8</oasis:entry>
         <oasis:entry colname="col7">78.0</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e2429">In order to get further insights into the seasonal variations, we also
calculated the average values for each month in the time series for every
isotopic and climatic parameter, while rainfall is reported as monthly
totals (Table 2). <inline-formula><mml:math id="M141" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O is relatively low during the summer
months, for instance with <inline-formula><mml:math id="M142" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">7.29</mml:mn></mml:mrow></mml:math></inline-formula> ‰ in September 2014
compared to the months of winter and spring with <inline-formula><mml:math id="M143" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.53</mml:mn></mml:mrow></mml:math></inline-formula> ‰ in April 2014 or <inline-formula><mml:math id="M144" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.66</mml:mn></mml:mrow></mml:math></inline-formula> ‰ in February 2015. Similarly,
the monthly rainfall total is less in winter and spring with 19.2 mm in
March 2014 and 29.2 mm in January 2015 compared to the summer months such as
July and August 2014 with 455.4 and 420.7 mm, respectively. As mentioned
before regarding the daily measurements, we also observe on the monthly
scale conditions which are more humid in the summer. We investigated the
relationship between the isotopic composition of precipitation (<inline-formula><mml:math id="M145" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O) and meteorological parameters (total monthly rainfall, average
relative humidity, and temperature) on a monthly scale. <inline-formula><mml:math id="M146" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O
and <inline-formula><mml:math id="M147" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H are strongly correlated (Pearson correlation
coefficient) with <inline-formula><mml:math id="M148" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.96</mml:mn></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M149" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">18</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M150" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value <inline-formula><mml:math id="M151" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.0001</mml:mn></mml:mrow></mml:math></inline-formula>, and 99 %
confidence level), whereas the relationship between <inline-formula><mml:math id="M152" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and
d-excess yields an <inline-formula><mml:math id="M153" display="inline"><mml:mi>r</mml:mi></mml:math></inline-formula> value of <inline-formula><mml:math id="M154" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.64</mml:mn></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M155" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">18</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M156" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value <inline-formula><mml:math id="M157" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.003</mml:mn></mml:mrow></mml:math></inline-formula>). A clear negative
correlation was determined between <inline-formula><mml:math id="M158" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and precipitation with
<inline-formula><mml:math id="M159" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.67</mml:mn></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M160" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">18</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M161" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value <inline-formula><mml:math id="M162" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.002</mml:mn></mml:mrow></mml:math></inline-formula>) and between <inline-formula><mml:math id="M163" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and
relative humidity with <inline-formula><mml:math id="M164" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.85</mml:mn></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M165" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">18</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M166" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value <inline-formula><mml:math id="M167" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.0001</mml:mn></mml:mrow></mml:math></inline-formula>).
<inline-formula><mml:math id="M168" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and temperature are not correlated with <inline-formula><mml:math id="M169" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.04</mml:mn></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M170" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">18</mml:mn></mml:mrow></mml:math></inline-formula>,
<inline-formula><mml:math id="M171" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value <inline-formula><mml:math id="M172" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.87</mml:mn></mml:mrow></mml:math></inline-formula>).</p>
      <p id="d1e2774">A relationship between isotopic value and the distance of the TC towards the
sampling site was found. The TCs' distance of up to 500 km to sampling site
and the precipitation isotope value are correlated with <inline-formula><mml:math id="M173" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.55</mml:mn></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M174" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">16</mml:mn></mml:mrow></mml:math></inline-formula>,
<inline-formula><mml:math id="M175" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value <inline-formula><mml:math id="M176" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.05</mml:mn></mml:mrow></mml:math></inline-formula>, and 99 % confidence level). This relationship
weakens with an increase in the distance from the sampling site: a distance
of 500 to 1000 km yields an <inline-formula><mml:math id="M177" display="inline"><mml:mi>r</mml:mi></mml:math></inline-formula> value of 0.2 (<inline-formula><mml:math id="M178" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">19</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M179" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value <inline-formula><mml:math id="M180" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.41</mml:mn></mml:mrow></mml:math></inline-formula>); the distance
of 1000 to 1500 km yields an <inline-formula><mml:math id="M181" display="inline"><mml:mi>r</mml:mi></mml:math></inline-formula> value of 0.18 (<inline-formula><mml:math id="M182" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">24</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M183" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value <inline-formula><mml:math id="M184" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.40</mml:mn></mml:mrow></mml:math></inline-formula>); and a
1500 to 2000 km distance results in an <inline-formula><mml:math id="M185" display="inline"><mml:mi>r</mml:mi></mml:math></inline-formula> value of 0.1 (<inline-formula><mml:math id="M186" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">21</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M187" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value <inline-formula><mml:math id="M188" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.69</mml:mn></mml:mrow></mml:math></inline-formula>).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><?xmltex \def\figurename{Figure}?><label>Figure 5</label><caption><p id="d1e2932">Complete time series of 186 precipitation samples taken between 10 March 2014 and 27 October 2015. <inline-formula><mml:math id="M189" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O data points associated
with TC activity are coloured in red. Other anomalously low <inline-formula><mml:math id="M190" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values were investigated using IMERG satellite precipitation data.
Point a: Rammasun, 16 July 2014, <inline-formula><mml:math id="M191" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13.84</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 83 mm.
Point b: Kalmaegi, 15 September 2014, <inline-formula><mml:math id="M192" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">11.39</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 85 mm.
Point c: Fung-Wong, 20 September 2014, <inline-formula><mml:math id="M193" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">12.16</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 175 mm.
Point d: Hagupit, 8–9 December 2014, <inline-formula><mml:math id="M194" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9.88</mml:mn></mml:mrow></mml:math></inline-formula> ‰, <inline-formula><mml:math id="M195" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10.62</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 40 mm.
Point e: Mekkhala, 19 January 2015, <inline-formula><mml:math id="M196" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10.77</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 22 mm.
Point f: Linfa, 7 July 2015, <inline-formula><mml:math id="M197" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 63 mm.
Point g: Twelve, 23 July 2015, <inline-formula><mml:math id="M198" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">7.7</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 68 mm.
Point h: Mujigae, 1 October 2015, <inline-formula><mml:math id="M199" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">7.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 51 mm.
Point i: Koppu, 19–20 October 2015, <inline-formula><mml:math id="M200" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8.7</mml:mn></mml:mrow></mml:math></inline-formula> ‰, <inline-formula><mml:math id="M201" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9.72</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 38, 26 mm.
Point 1: storm passing by, 19 June 2014, <inline-formula><mml:math id="M202" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10.44</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 6 mm.
Point 2: large rain areas, 27 August 2014, <inline-formula><mml:math id="M203" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">12.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 21 mm.
Point 3: storm passing by, 15 November 2014, <inline-formula><mml:math id="M204" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10.58</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 3 mm.
Point 4: large rain areas, 22–23 June 15, <inline-formula><mml:math id="M205" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10.76</mml:mn></mml:mrow></mml:math></inline-formula> ‰, <inline-formula><mml:math id="M206" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">11.52</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 2, 4 mm.
Point 5: heavy rainfall, 13 August 2015, <inline-formula><mml:math id="M207" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9.96</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 80 mm.
Point 6: heavy rainfall, 18 August 2015, <inline-formula><mml:math id="M208" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9.26</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 13 mm.
Point 7: local convection, 16 September 2015, <inline-formula><mml:math id="M209" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8.28</mml:mn></mml:mrow></mml:math></inline-formula> ‰, 47 mm.
Please note that the date format in this figure is month/year.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://nhess.copernicus.org/articles/22/213/2022/nhess-22-213-2022-f05.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Precipitation isotope evolution during TC events</title>
      <?pagebreak page219?><p id="d1e3164">Overall, precipitation isotopes associated with TCs mark the lower range of
<inline-formula><mml:math id="M210" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values during the study period. Especially during the 2014
season, precipitation with low isotope values mostly occurred throughout the
passage of TCs. For instance, Rammasun led to the lowest <inline-formula><mml:math id="M211" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> value
(Fig. 5, point a, <inline-formula><mml:math id="M212" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13.84</mml:mn></mml:mrow></mml:math></inline-formula> ‰) of the whole study period,
while other TCs such as Fung-Wong (Fig. 5, point c, <inline-formula><mml:math id="M213" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">12.16</mml:mn></mml:mrow></mml:math></inline-formula> ‰), Kalmaegi (Fig. 5, point b, <inline-formula><mml:math id="M214" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">11.39</mml:mn></mml:mrow></mml:math></inline-formula> ‰), or Hagupit (Fig. 5, point d, <inline-formula><mml:math id="M215" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9.88</mml:mn></mml:mrow></mml:math></inline-formula> ‰) caused other negative excursions in isotopic values.
The 2015 season is characterized by on average a slightly higher isotopic
enrichment during the summer months with heavy rainfall. Nonetheless, a
similar noticeable isotope signal is visible with low <inline-formula><mml:math id="M216" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values
clustered along the lower end of the sample range, for example, caused by
Linfa (Fig. 5, point f, <inline-formula><mml:math id="M217" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰) or Koppu (Fig. 5, point i, <inline-formula><mml:math id="M218" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8.7</mml:mn></mml:mrow></mml:math></inline-formula> ‰). The other TCs that occurred during the
study period and were investigated by us were Mekkhala (Fig. 5, point e,
<inline-formula><mml:math id="M219" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10.77</mml:mn></mml:mrow></mml:math></inline-formula> ‰), Twelve (Fig. 5, point g, <inline-formula><mml:math id="M220" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">7.7</mml:mn></mml:mrow></mml:math></inline-formula> ‰), and Mujigae (Fig. 5, point h, <inline-formula><mml:math id="M221" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">7.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰). However, relatively negative isotope samples (Fig. 5) also originated from non-TC rainfall systems. Those events are discussed
below.</p>
      <p id="d1e3288">Out of the nine TCs that occurred within a 500 km radius from the sampling
site, Rammasun and Kalmaegi left clearly observable, distinct isotopic
signatures during their approach and dissipation, which we will therefore
present in more detail in the next paragraphs. Typhoon Hagupit (Fig. 5,
point d) similarly led to a clear isotopic evolution pattern during its time
of occurrence in the Philippines and is shown in the Supplement (Sect. S1).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><?xmltex \currentcnt{6}?><?xmltex \def\figurename{Figure}?><label>Figure 6</label><caption><p id="d1e3293">Accumulated precipitation from IMERG satellite data and TC tracks
from IBTrACS for <bold>(a)</bold> Rammasun with precipitation accumulation for 14–17 July 2014 and <bold>(b)</bold> Kalmaegi with accumulated precipitation for 12–15 September 2014.
Made with base layers from Natural Earth. Please note that the date format in this figure is day/month/year.</p></caption>
          <?xmltex \igopts{width=483.69685pt}?><graphic xlink:href="https://nhess.copernicus.org/articles/22/213/2022/nhess-22-213-2022-f06.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7" specific-use="star"><?xmltex \currentcnt{7}?><?xmltex \def\figurename{Figure}?><label>Figure 7</label><caption><p id="d1e3311">Isotopic signature from TCs during their passage to the
Metropolitan Manila sampling site. <inline-formula><mml:math id="M222" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O (blue), distance
from the storm's centre to sampling location (green), and daily rainfall amount
(red) for <bold>(a)</bold> Rammasun and <bold>(b)</bold> Kalmaegi. Please note that the date format in this figure is day/month/year.</p></caption>
          <?xmltex \igopts{width=483.69685pt}?><graphic xlink:href="https://nhess.copernicus.org/articles/22/213/2022/nhess-22-213-2022-f07.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8" specific-use="star"><?xmltex \currentcnt{8}?><?xmltex \def\figurename{Figure}?><label>Figure 8</label><caption><p id="d1e3339">Spatiotemporal evolution of <inline-formula><mml:math id="M223" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O isotopes. Centred on the
Metropolitan Manila collection site, different radii provide information on
distance between the storm's centre to Metropolitan Manila. <inline-formula><mml:math id="M224" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O
values are colour-coded. <bold>(a)</bold> Rammasun.<bold>(b)</bold> Kalmaegi. Please note that the date format in this figure is day/month/year.</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://nhess.copernicus.org/articles/22/213/2022/nhess-22-213-2022-f08.png"/>

        </fig>

      <p id="d1e3376">Typhoon Rammasun's rainfall intensity based on the IMERG precipitation
data together with its track from IBTrACS is shown in Fig. 6a. Typhoon
Rammasun stands out in our study period, as it moved straight towards the
National Capital Region of the Philippines, resulting in a direct hit.
Rammasun, locally named Glenda, made landfall in the Bicol Region of
southern Luzon on 15 July, with wind speeds of about 160 km/h. On 16 July,
it passed south of Metropolitan Manila, 50 km from our sampling site, with
maximum winds of 130 km/h, gradually losing strength over land. As Rammasun
approached on 15 July, the precipitation exhibited a relatively high <inline-formula><mml:math id="M225" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O value of <inline-formula><mml:math id="M226" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:math></inline-formula> ‰, while rainfall was weak (Fig. 7a). On
16 July, the <inline-formula><mml:math id="M227" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O value shifted to <inline-formula><mml:math id="M228" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13.84</mml:mn></mml:mrow></mml:math></inline-formula> ‰, while
the typhoon's track was the closest to our sampling site, and rainfall amount
was high. As Rammasun moved away, precipitation isotopes became more
positive, and the rainfall amount decreased. The characteristic isotopic
evolution with time related to Rammasun's distance and rainfall intensities
can be seen in Fig. 8a, where the different radii indicate the distance to
the sampling site, and the strong isotopic depletion observed on 16 July is
also evident. As Rammasun with its storm centre tracked towards the
northwest and away from Metropolitan Manila, our precipitation samples were
relatively isotopically enriched for the following 2 d, namely <inline-formula><mml:math id="M229" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9.12</mml:mn></mml:mrow></mml:math></inline-formula> ‰ on 17 July and <inline-formula><mml:math id="M230" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn><mml:mo>,</mml:mo><mml:mn mathvariant="normal">26</mml:mn></mml:mrow></mml:math></inline-formula> ‰ on 18 July.</p>
      <p id="d1e3446">Typhoon Kalmaegi, locally named Luis, was the first typhoon to make landfall
in the Philippines, 2 months after Rammasun. Kalmaegi reached typhoon
intensity on 13 September, making landfall the following day in northern
Luzon, with maximum wind speeds of about 120 km/h. Kalmaegi tracked
relatively far away from the sampling site (about 350 km), but the
accumulated rainfall it produced was centred south of the track, placing it
considerably closer to the National Capital Region (Fig. 6b). Despite the
distance of the eye from the sampling site, a characteristic isotopic
pattern was visible, with the most negative <inline-formula><mml:math id="M231" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O value of
<inline-formula><mml:math id="M232" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">11.39</mml:mn></mml:mrow></mml:math></inline-formula> ‰ on 15 September, coincident with the highest
rainfall amount (Fig. 7b). The following day, <inline-formula><mml:math id="M233" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values returned to
higher values with the increase in distance from the eye. This is also seen
in a spatial representation in Fig. 8b, visualizing the track of Kalmaegi
and the respective <inline-formula><mml:math id="M234" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O<?pagebreak page220?> values. Kalmaegi was first approaching
the sampling site on 14 September and passed away on 15 and 16 September.
The lowest <inline-formula><mml:math id="M235" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O value was observed on 15 September and is indicated
in the figure in dark blue.</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Discussion</title>
<sec id="Ch1.S4.SS1">
  <label>4.1</label><title>Stable isotopes of precipitation – a possible tracer for TCs</title>
      <p id="d1e3519">As stable water isotopes fractionate during the physical process of
evaporation and condensation, they serve as effective tracers in the
hydrological cycle
(Dansgaard,
1964; He et al., 2018; Risi et al., 2008; Tremoy et al., 2014). Here, we
have demonstrated that stable water isotopes can possibly be used to
identify TC activity in the Southeast Asian region by excursions in <inline-formula><mml:math id="M236" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, providing evidence and supporting the hypothesis that TCs may
leave a clear isotopic signal in the Philippines. The strong isotopic
depletion is due to high condensation efficiencies in cyclonic convective
rainbands, leading to extensive fractionation. This is particularly
pronounced in intense, large-scale TCs
(Lawrence, 1998; Lawrence and Gedzelman, 1996).
In the previous section, we presented our findings of precipitation
isotope ratios associated with typhoon activities affecting Metropolitan
Manila during the study period of March 2014 to October 2015. Based on our
time series, we therefore argue that for the Philippines, the lowest
measured isotope value likely indicates the occurrence of a TC, such as is
the case for Typhoon Rammasun (Fig. 5). Similarly, other anomalously low
<inline-formula><mml:math id="M237" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values at our site are caused by TCs making landfall or
passing by.</p>
      <?pagebreak page221?><p id="d1e3544">Individual TCs (Rammasun and Kalmaegi) were characterized by consistent
isotopic excursions to very negative <inline-formula><mml:math id="M238" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values in a range of up to
<inline-formula><mml:math id="M239" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9</mml:mn></mml:mrow></mml:math></inline-formula> ‰ compared to the mean isotopic value of <inline-formula><mml:math id="M240" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5.29</mml:mn></mml:mrow></mml:math></inline-formula> ‰ (Figs. 7 and 8). A TC approaching the sampling site had
relatively higher isotope values than at its later stages when it was
closest to the site in Metropolitan Manila. When at its closest, strong
rainfall together with increased fractionation depleted precipitation
isotopes, leading to a distinct drop in isotope value. Such a strong
negative isotopic shift in precipitation has been previously observed in
other regions
(Fudeyasu et al.,
2008; Lawrence and Gedzelman, 1996; Munksgaard et al., 2015; Xu et al.,
2019). As the TC moved away and rainfall intensities weakened, <inline-formula><mml:math id="M241" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O in precipitation became again more positive, likely due to
evaporative effects (Munksgaard et
al., 2015; Xu et al., 2019).</p>
      <p id="d1e3589">As the strongest TC in terms of wind speeds, damage costs, and fatalities,
Typhoon Rammasun reduced <inline-formula><mml:math id="M242" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values most during our study period, to
<inline-formula><mml:math id="M243" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13.84</mml:mn></mml:mrow></mml:math></inline-formula> ‰. Similarly, Typhoon Kalmaegi led to extensive
damage and caused a significantly negative excursion in precipitation of
<inline-formula><mml:math id="M244" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values to <inline-formula><mml:math id="M245" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">11.39</mml:mn></mml:mrow></mml:math></inline-formula> ‰, suggesting that the
lowest isotope values might indicate the occurrence of the strongest TC at
that time at our site in the Philippines. We note that our isotopic
measurements are similar to observations elsewhere. For example, the range
of <inline-formula><mml:math id="M246" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values caused by Typhoon Shanshan affecting the
subtropical Ishigaki Island was <inline-formula><mml:math id="M247" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M248" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13</mml:mn></mml:mrow></mml:math></inline-formula> ‰
(Fudeyasu et al., 2008); Tropical Cyclone Ita
led to a range of <inline-formula><mml:math id="M249" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4.8</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M250" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">20.2</mml:mn></mml:mrow></mml:math></inline-formula> ‰ in northeastern
Australia (Munksgaard et al., 2015); several TCs
which made landfall in Texas resulted in isotope values from <inline-formula><mml:math id="M251" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3.9</mml:mn></mml:mrow></mml:math></inline-formula> ‰ to <inline-formula><mml:math id="M252" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">14.3</mml:mn></mml:mrow></mml:math></inline-formula> ‰ (Lawrence and Gedzelman, 1996); and
hurricanes that affected Puerto Rico and southern Texas were found to
deplete <inline-formula><mml:math id="M253" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values up to <inline-formula><mml:math id="M254" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">18</mml:mn></mml:mrow></mml:math></inline-formula> ‰ (Lawrence, 1998). The lowest value resulting from
Typhoon Phailin on the Andaman Islands was reported to be <inline-formula><mml:math id="M255" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">5.5</mml:mn></mml:mrow></mml:math></inline-formula> ‰, and Cyclone Lehar depleted the precipitation sample
to <inline-formula><mml:math id="M256" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">17.1</mml:mn></mml:mrow></mml:math></inline-formula> ‰ (Chakraborty et al., 2016). For TCs
within a distance of up to 500 km from the sampling site at the University
of the Philippines Diliman in Metropolitan Manila, we measured an isotopic
range of <inline-formula><mml:math id="M257" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">7.7</mml:mn></mml:mrow></mml:math></inline-formula> ‰ (Typhoon Koppu) to <inline-formula><mml:math id="M258" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">13.84</mml:mn></mml:mrow></mml:math></inline-formula> ‰ (Typhoon Rammasun). Despite the overall comparability
to our measurements, differences exist. The lowest values observed in some
studies are considerably more negative than at our site
(Lawrence, 1998; Munksgaard
et al., 2015). However, we attribute these differences to a variety of
features, such as the specific climatic condition at each site and differences
in temperature, humidity, and altitude or latitude, which are likely
contributing factors to the observed isotopic variation by altering isotopic
fractionation. Further, rainout history, the location of typhoon tracks,
topography, and respective strength of each TC as well as its distance to the
sampling site most likely have a significant influence as well
(Fudeyasu
et al., 2008; Good et al., 2014; Munksgaard et al., 2015; Xu et al., 2019).</p>
      <p id="d1e3768">We used IMERG satellite precipitation data to assess why other very low
isotopic excursions occurred on various days (Fig. 5). IMERG data with their
fine spatiotemporal resolution allow for the identification of convective
rainfall areas and the passage of TCs and other rain systems (Fig. 6). Our
analysis shows that precipitation events with anomalously low isotope
signals unassociated with TCs are largely related to local, strong
convective rainfall events or large-scale and slow-moving rain areas passing
over the National Capital Region. Therefore, the degree of convection is
responsible for the other observed low <inline-formula><mml:math id="M259" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O outliers that are
not related to cyclone rainfall, as strong convection and long stratiform
rainfall leads to intense fractionation
(He et al., 2018;
Risi et al., 2008; Tremoy et al., 2014). Contrarily, we speculate that the
more positive isotope values clustering along the higher end of the sample
spectrum around 0 ‰ are associated with local, short
convective rainfall events and light-intensity rain as confirmed with IMERG
satellite precipitation data. Additionally, the PAGASA rain gauge data
indicate that rainfall amounts are very low during days with such very
enriched isotope samples, such as 0.3 mm/d for the highest recorded sample
of 4 ‰ on 9 April 2014. Interestingly, TCs at our<?pagebreak page222?> site
were found to be related to low isotope values together with high rainfall
amounts (Fig. 5), while the majority of other low isotopic values
unassociated with TCs were characterized by on average lesser rainfall
amounts. This possibly indicates that TCs in the Philippines, besides using
for instance modern-day satellite or radar data, can be detected using these
two parameters, i.e. strong isotopic depletion coupled with high rainfall
amounts.</p>
      <p id="d1e3783">The aforementioned local convective precipitation events have the potential
to induce a signal of very negative <inline-formula><mml:math id="M260" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, which is not related
to TC activities. We therefore label such a signal as a “false non-TC
signal”, as it is induced by non-TC rainfall. This results in the fact that
TCs occurring during our study period do not entirely cluster along the
lowest range of isotope values as seen in Fig. 5. Nevertheless, Typhoon
Rammasun caused a clear drop in <inline-formula><mml:math id="M261" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and stands out in the
dataset. This might be the case because Rammasun's track and heavy rainfall
come in closest proximity (50 km) to the sampling site. Other TCs occurring
within the 500 km radius did not lead to such a clear negative isotopic
signature, likely because these typhoons did not pass the sampling site at
all or because heavy rainfall occurred elsewhere within the TC rainfall system (see
Sect. S2  in the Supplement for their tracks and accumulated rainfall areas). Some of these TCs have
intense rainfall areas over other parts of the Philippines and are
characterized by a variable track, likely influenced by land interactions.
Land interaction reduces TC strength and can lead to rainout due to
orographic effects induced by the north–south-oriented mountain ranges
(Park et al.,
2017; Xie and Zhang, 2012; Xu et al., 2019). Especially Typhoon Koppu rained
out before making landfall and abruptly changed its track, instead of
passing by Metropolitan Manila. Similarly, Typhoon Mekkhala's intense
rainfall occurred along the eastern coasts before it started to dissipate.
Evidently, due to these factors the isotope values associated with those TCs
were not as negative as during Rammasun. Therefore, a TC, which is
relatively far away from the sampling site, produces an isotope signal that
is not as clear and as negative, thus averaging out between the other low
values from rain systems unassociated with TC.</p>
</sec>
<sec id="Ch1.S4.SS2">
  <label>4.2</label><title>Drivers of isotopic variation at Metropolitan Manila</title>
      <p id="d1e3816"><inline-formula><mml:math id="M262" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O, <inline-formula><mml:math id="M263" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H, and the second parameter of d-excess all show
seasonal variabilities and are influenced by several climatic factors,
including precipitation amount, temperature, and relative humidity. The
scale of their influence varies depending on daily or monthly values. The
results indicate that <inline-formula><mml:math id="M264" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O on daily levels is not influenced by
temperature, relative humidity, or precipitation amount (Fig. 2) as drivers
of isotopic variability. Instead, we speculate that other processes, such as
large-scale convection and processes at the moisture source region, might
influence stable isotopes of precipitation at our study site
(Conroy et al.,
2016; He et al., 2018; Kurita, 2013). Interestingly, <inline-formula><mml:math id="M265" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O is
not affected by precipitation amount on short timescales (Fig. 4), which has
also been previously confirmed in other tropical regions, suggesting that
the tropical amount effect is not reflected on daily timescales
(Belgaman
et al., 2016; Dansgaard, 1964; He et al., 2018; Kurita et al., 2009;
Marryanna et al., 2017; Permana et al., 2016). However, comparing monthly
<inline-formula><mml:math id="M266" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O to <inline-formula><mml:math id="M267" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>H and d-excess and to monthly average
precipitation, relative humidity, and temperature, the results are clearly
different (Table 2). These monthly observations show close relationships
with each other; especially <inline-formula><mml:math id="M268" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and precipitation amount are
linked (see Sect. 3.1). The close relationship between these two
parameters can be attributed to the tropical amount effect
(Aggarwal et
al., 2012; Bowen, 2008; Conroy et al., 2016). The relatively close
relationship with <inline-formula><mml:math id="M269" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.67</mml:mn></mml:mrow></mml:math></inline-formula> between monthly <inline-formula><mml:math id="M270" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O and monthly
total precipitation might be likely due to the influence of regional
convective activities on the isotopic composition of precipitation
(Bony
et al., 2008; He et al., 2018; Moerman et al., 2013; Risi et al., 2008).</p>
</sec>
<sec id="Ch1.S4.SS3">
  <label>4.3</label><title>Distance of TCs from Metropolitan Manila</title>
      <p id="d1e3929">Our observations provide details on the spatial distance from the collection
site towards TCs' centres, as our findings indicate that the distance from
the storm's centre to the sampling site impacts the isotopic value (see
Sect. 3.1). This suggests that a TC more than 500 km away from the
sampling site has no influence on precipitation isotopes
(Munksgaard et al., 2015). Thus, the closer the
TC is to the sampling site, the more negative the isotope signal and the
larger the <inline-formula><mml:math id="M271" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> change are. This relationship might provide information on
storm structure and intensity, as the intensity increases with the proximity of
the TC to the sampling location. We thus confirm that the isotope value at
our location is a function of the closest approach of the storm's centre to
the sampling site (Lawrence and Gedzelman, 1996).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9"><?xmltex \currentcnt{9}?><?xmltex \def\figurename{Figure}?><label>Figure 9</label><caption><p id="d1e3941">Spatiotemporal variation of isotopes related to TC activity within
2000 km, with different radii indicating the distance towards Metropolitan
Manila. <inline-formula><mml:math id="M272" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values are colour-coded.</p></caption>
          <?xmltex \igopts{width=213.395669pt}?><graphic xlink:href="https://nhess.copernicus.org/articles/22/213/2022/nhess-22-213-2022-f09.png"/>

        </fig>

      <?pagebreak page223?><p id="d1e3961">Figure 9 displays all the precipitation samples associated with TC presence
and activities within a 2000 km radius from Metropolitan Manila and further
highlights the relationship between distance and isotopic depletion,
additionally providing a spatial indication of a TC's quadrants and its
tracks relative to the location of the sampling site. The strongest depletion
occurs within the 500 km radius. However, two relatively negative outliers
are located within a 1000 to 1500 km radius in the northwest quadrant (see
points a and b in Fig. 9). These two samples were taken during the passage
of Tropical Storm Kujira on 22 and 23 June 2015 (Fig. 5),
which was more than 1000 km away from Metropolitan Manila travelling east
along the coast of Vietnam as seen with IBTrACS data. We investigated these
two samples with IMERG satellite precipitation data and identified them as a
part of a mesoscale system, with strong convective cells delivering intense
rainfall, leading to distinct isotopic depletion and inducing a false
non-TC signal of a very negative <inline-formula><mml:math id="M273" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O value, which is not related to
TC activity.</p>
</sec>
<sec id="Ch1.S4.SS4">
  <label>4.4</label><title>Cyclone track's rainfall intensity</title>
      <p id="d1e3983">IMERG satellite precipitation data also reveal that the highest rainfall
intensities occur at the left side of the TC track for all the TCs within the
500 km radius, except for Hagupit and Mekkhala, which are more complex cases
(Fig. 6a and b and Supplement Sects. S1 and S2). This is in contrast to the results from
Villarini et al. (2011), who found that
the largest rainfall accumulation appeared on the right side of the
hurricane tracks. They also noted that large rainfall amounts occurred far
away from the storm's track, which we can confirm and quantify with our
observations. The largest rainfall totals vary in a range of 50 to 150 km
away from the storm's centre depending on the TC. For Kalmaegi the intense
rainfall areas are up to 150 km away from the storm's centre. These areas
with the highest rainfall totals should most likely coincide with the most
negative isotope value, indicating that the strongest depletion occurs in
the outer cyclonic rainbands. This is consistent with previous findings
(Gedzelman et
al., 2003; Lawrence and Gedzelman, 1996; Munksgaard et al., 2015). However,
Fudeyasu et al. (2008) observed the highest
isotope values in the inner eye wall, i.e. in close proximity to the storm's
centre. We could not investigate this further, as no TC passed by our site in
a distance of about 20 km, which is the size of a typical typhoon's eye
(Weatherford and Gray, 1988).</p>
</sec>
<sec id="Ch1.S4.SS5">
  <label>4.5</label><title>Implications for paleoclimate studies</title>
      <p id="d1e3995">Isotope proxies from paleoarchives such as tree rings and speleothems have
been utilized to reconstruct past cyclone activities
(Frappier,
2013; Frappier et al., 2007; Miller et al., 2006; Nott et al., 2007). For
instance, stalagmites yielded a record of weekly temporal resolution with
negative isotopic excursions related to TC activity
(Frappier et al., 2007). Such a high
temporal resolution from stalagmites makes our in situ measurements very
comparable, highlighting the potential to use both in conjunction.
Similarly, high-resolution tree-ring isotope analysis identified the
occurrence of Hurricane Ivan and Hurricane Frances in 2004, which both
resulted in the lowest observed precipitation isotope values for that year
(Li et al., 2011).
Nevertheless, it is important to consider possible limitations at the study
site that arise in paleotempestology, such as sea level change or the disruption
of sedimentological records through floods or tsunamis. These need to be
evaluated when comparing precipitation isotopes related to TCs with other
proxy records such as speleothems and coastal deposits and when choosing the
study area (Oliva et al., 2017). However, the
aforementioned paleotempestology studies suffer from uncertainty regarding
parameters such as TC intensity and distance to the storm's centre affecting
the isotope signal. Our study provides further information on these
parameters, as we hypothesize that immediate proximity of a TC results in
very low <inline-formula><mml:math id="M274" display="inline"><mml:mrow><mml:msup><mml:mi mathvariant="italic">δ</mml:mi><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>O values. Therefore, we might aid with a better
interpretation of paleoarchives. Moreover, these studies are limited in
number and only focus on a few regions affected by TCs, such as Central
America and the southeastern USA (Frappier et al., 2007; Miller et al.,
2006). However, more paleotempestology studies investigating paleoarchives
related to typhoon footprints covering different regions and countries would
provide a better understanding of past TC activity, ultimately resulting in
better and more accurate climate reconstructions. TC projections related to
climate change could also be improved, which is especially relevant for
decision makers dealing with TC-related impacts and damages. Our in situ
isotope measurements provide baseline data input in an understudied tropical
region, providing isotopic data of TC occurrence and quantifying the
isotopic depletion associated with TC activity. Further, our 19-month
dataset suggests that the lowest measured isotope value at the Philippines
study site is associated with TC activity, resulting in the distinct
negative isotopic shift in the time series (Fig. 5). As rainout history,
topography, distance of the track, or rainfall unassociated with TCs can induce a
weak or false non-TC signal, it is important to choose stalagmites or
trees as archives based on their location, ideally covering a spatial
gradient, thus capturing a TC in its full size.</p>
</sec>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <label>5</label><title>Conclusions</title>
      <p id="d1e4019">Our study demonstrated that a strong, high-energy TC with a track directly
approaching and hitting the sampling site leads to a clear isotopic signal
in a time series in the Philippines. If the TC is further away, such as more
than 500 km from the site, or heavy TC rainfall occurred elsewhere prior of
making landfall, the signal is not as clear and might average out between
other rainfall events. Other strong convective rainfall events unassociated
with TCs may result in similarly low isotope values, and we label these as a
weak or false non-TC<?pagebreak page224?> signal. Therefore, the distance of a TC to the
sampling site is a key factor in influencing the isotope signal, and such a
spatial component needs to be considered when interpreting the isotope
signal. However, a longer time series isotope record would help to better
constrain controlling factors, such as the influence of topography on
high-energy TCs. To what extent mountain ranges and low-elevation coastal
areas shape the TC-induced isotope signal needs further investigation. Based
on our findings we conclude that the location of precipitation sample
collection needs to be chosen strategically. Ideally, several rainwater
collection stations should be operated, covering a wide geographical range
such as stretching from northern Luzon to its south. With such a spatial-gradient coverage, a TC would likely be captured in its full size.
Consequently, we aim to expand our time series spatially and temporally.</p>
      <p id="d1e4022">Our dataset is the first of such a record in the Philippines and provides much
needed data in scarcely sampled Southeast Asia. It can be used as a baseline
in paleotempestology studies reconstructing past TC history, in conjunction
with tree-ring and speleothem datasets, as our data suggest that for
Metropolitan Manila the lowest measured isotope value is caused by typhoon
activity. A higher precipitation sampling frequency on sub-daily levels at
several locations would yield more detailed constraints on TC parameters
such as storm structure, which we aim to realize in the future.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e4029">The underlying research data can be accessed via the Supplement, as well as in Knapp et al. (2010a, <ext-link xlink:href="https://doi.org/10.7289/V5NK3BZP" ext-link-type="DOI">10.7289/V5NK3BZP</ext-link>) and Huffman et al. (2019, <ext-link xlink:href="https://doi.org/10.5067/GPM/IMERGDF/DAY/06" ext-link-type="DOI">10.5067/GPM/IMERGDF/DAY/06</ext-link>).</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d1e4038">The supplement related to this article is available online at: <inline-supplementary-material xlink:href="https://doi.org/10.5194/nhess-22-213-2022-supplement" xlink:title="pdf">https://doi.org/10.5194/nhess-22-213-2022-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e4047">DJ analysed the data and wrote the manuscript. BXY
contributed to the data analysis and improved the manuscript. ADS
conceived the idea and reviewed and improved the manuscript. SH
provided advice and reviewed and improved the manuscript. DLMC and
FPS collected the precipitation samples and improved the
manuscript. NFG reviewed and improved the manuscript.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e4053">The contact author has declared that neither they nor their co-authors have any competing interests.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e4059">This research was supported by the Earth Observatory of Singapore (EOS) via its
funding from the National Research Foundation Singapore and the
Ministry of Education of Singapore under the Research Centres of Excellence initiative.
This work comprises EOS contribution no. 422. This study is also the part
of the IAEA Coordinated Research Project (CRP code: F31004) on “Stable Isotopes
in Precipitation and Paleoclimatic Archives in Tropical Areas to Improve
Regional Hydrological and Climatic Impact Models” (IAEA Research
Agreement no. 17980).</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e4064">This research has been supported by the National Research Foundation Singapore and the Ministry of Education of Singapore.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d1e4070">Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e4076">This paper was edited by Paolo Tarolli and reviewed by four anonymous referees.</p>
  </notes><ref-list>
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